Why is 256x256 important for app icons?
256x256 is the largest size in the standard Windows icon set and is especially important on high-DPI monitors, where the operating system displays desktop icons at very large sizes. Including a 256x256 version in your icon file ensures Windows scales the icon down for smaller contexts rather than scaling a small icon up, which would look blurry. Most icon guidelines recommend 16, 32, 48 and 256 pixels as the minimum complete set.